| Autor: |
Wei, Lin-Wen, Ma, Zhan-Cai, Wang, Zhao-Qing, Zhao, Yu, Huang, Yuan |
| Předmět: |
|
| Zdroj: |
Synthesis; Dec2023, Vol. 55 Issue 23, p3954-3960, 7p |
| Abstrakt: |
This article discusses the development of a cobalt-catalyzed enantioselective alkynylation reaction for oxabicyclic alkenes. The researchers optimized the reaction conditions and found that chlorobenzene as a solvent and CoBr2 as a catalyst resulted in the highest yield and enantioselectivity. The method was successfully used to produce a variety of chiral cyclic homopropargylic alcohols. The document provides detailed information about the experimental procedures, results, and characterization of the synthesized compounds using various analytical techniques. The absolute configurations of the compounds were determined by reference to previous literature. The supporting information for the article is available online. [Extracted from the article] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
