| Autor: |
Gillen, Jonathan H., Moore, Connor A., Vuong, My, Shajahan, Juvairia, Anstey, Mitchell R., Alston, Jeffrey R., Bejger, Christopher M. |
| Předmět: |
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| Zdroj: |
Chemical Communications; 4/21/2022, Vol. 58 Issue 31, p4885-4888, 4p |
| Abstrakt: |
Here, we show for the first time that main-chain organometallic polymers (MCOPs) can be prepared from Janus N-heterocyclic carbene (NHC) linkers and polynuclear cluster nodes. The crosslinked framework Co4S4-MCOP is synthesized via ligand displacement reactions and undergoes reversible electron transfer in the solid state. Discrete molecular cluster species can be excised from the framework by digesting the solid in solutions of excess monocarbene. Finally, we demonstrate a synthetic route to monodisperse framework particles via coordination modulation. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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