| Autor: |
Wei, Lanfeng, Bai, Wenbo, Hu, Zhiyan, Yang, Zhiyong, Xu, Liang |
| Předmět: |
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| Zdroj: |
Chemical Communications; 11/18/2023, Vol. 59 Issue 89, p13344-13347, 4p |
| Abstrakt: |
The oxidation process is widely explored and used to synthesize diverse organic chemicals. Herein, a unified metal-free photooxidative platform for the cleavage of C–heteroatom bonds has been developed. In these reactions, the aminoquinolate diarylboron (AQDAB) complex is utilized as the photocatalyst, instigating the oxidation process induced by visible light. The cleavage of C–heteroatom bonds can be achieved chemoselectively, affording the formal carbonylation product of C–N, C–S, and C–Se bonds. This method provides a channel for connecting amines, thiols, or selenides with the carbonyl compounds directly, broadening the potential applications of oxidation as a synthetic tool. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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