Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate.

Autor: Traoré, Bocar, Diallo, Waly, Sidibé, Mamadou, Diop, Libasse, Plasseraud, Laurent, Cattey, Hélène
Předmět:
Zdroj: Acta Crystallographica Section E: Crystallographic Communications; Nov2023, Vol. 79 Issue 11, p1003-1007, 11p
Abstrakt: The title salt, C14H16N+⋅C6H7AsNO3-⋅H2O or [(C6H5CHL)2NH2][H2NC6H4-As(OH)O2]⋅H2O, (I), was synthesized by mixing an aqueous solution of (4-aminophenyl)arsonic acid with an ethanolic solution of dibenzylamine at room temperature. Compound I crystallizes in the monoclinic P21/c space group. The three components forming I are linked via N--H⋯O and O--H⋯O intermolecular hydrogen bonds, resulting in the propagation of an infinite zigzag chain. Additional weak interactions between neighbouring chains, such as π- π and N--H⋯O contacts, involving phenyl rings, -NH2 and -As(OH)O3 functions, and H2O, respectively, lead to a three-dimensional network. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index