| Autor: |
Mazalov, L., Trubina, S., Fomin, E., Oglezneva, I., Parygina, G., Bausk, N., Igumenov, I. |
| Předmět: |
|
| Zdroj: |
Journal of Structural Chemistry; Sep2004, Vol. 45 Issue 5, p800-807, 8p |
| Abstrakt: |
The Cu(acac)2 complex was investigated by X-ray emission and XANES spectroscopy using synchrotron radiation. Structural data for the complex were obtained in chloroform solution and C2F matrix. The experimental spectra and their fitting on a single scale of binding energies point to possible relaxation effects. As shown by model quantum-chemical calculations, the structure and energy position of the LUMOs constructed from the vacant metal 4 p, 5 p AOs strongly depends on the nature of the nearest environment. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
