Mixed Anionoarylation of Tetramethylene and Diethylene Glycol Diacrylates.

Autor: Grishchuk, B. D., Baranovskii, V. S., Gorbovoi, P. M.
Předmět:
Zdroj: Russian Journal of General Chemistry; Apr2005, Vol. 75 Issue 4, p613-616, 4p
Abstrakt: The example of tetramethylene and diethylene glycol diacrylates was used to accomplish the first mixed anionoarylation. The reaction of diazonium salts with these unsaturated compounds gave chloroarylation adducts by one multiple bond: 1-acryloyloxy-4-(2-chloro-3-arylpropyonyloxy)butanes and 1-acryl-oyloxy-2-[2-(2-chloro-3-arylpropyonyloxy)ethoxy]ethanes. The latter were subjected to thiocyanatoarylation to obtain diadducts: 1-(2-chloro-3-arylpropyonyloxy)-4-(2-thiocyanato-3-arylpropyonyloxy)butanes and 1-(2-chloro-3-arylpropyonyloxy)-2-[2-(2-thiocyanato-3-arylpropyonyloxy)ethoxy]ethanes. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index