Boryl Acrylaldehyde: An Elusive Member of the α-Boryl Aldehyde Class of Reagent.

Autor: Trofimova, Alina, Brien, Chelsey, Trinchera, Piera, Tien, Chieh-Hung, Yudin, Andrei K.
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Zdroj: Synlett; Nov2023, Vol. 34 Issue 18, p2239-2243, 5p
Abstrakt: 19 Boryl MIDA Aldehyde 3c To an oven-dried round-bottom flask equipped with a magnetic stir bar was added MIDA boronate 8 (100 mg, 0.44 mmol, 1.0 equiv) dissolved in anhydrous MeCN (0.1 M). Boron, boryl aldehydes, hemilability, amphoteric molecules, oximes, boryl hydrazones, boryl Keywords: boron; boryl aldehydes; amphoteric molecules; hemilability; boryl; oximes; boryl hydrazones EN boron boryl aldehydes amphoteric molecules hemilability boryl oximes boryl hydrazones 2239 2243 5 10/31/23 20231127 NES 231127 Graph Matteson homologation is a powerful method for the synthesis of organoboron compounds. 22 Boryl MIDA Oxime 9 To a round-bottom flask equipped with a magnetic stir bar was added boryl MIDA aldehyde 3c (23 mg, 0.1 mmol, 1.0 equiv). [Extracted from the article]
Databáze: Complementary Index