| Abstrakt: |
The use of bulky 1,3,2-diazaborolyl N-substituents has allowed the synthesis of the complete series of ferrocene-based N-heterocyclic tetrylenes fc[(N{B})2E] (fc = 1,1′-ferrocenediyl, {B} = (HCNC6H3-2,6-iPr2)2B, E = Si–Pb). The silylene fc[(N{B})2Si] is inert towards NH3, CO2 or N2O under ambient conditions and thus significantly less reactive than the N-aryl homologue fc[(NC6H3-2,6-iPr2)2Si]. In accord with its higher reactivity, computational results indicate a more pronounced ambiphilicity of fc[(NC6H3-2,6-iPr2)2Si]. Our computational investigation of the model compound fc[(NBMe2)2Si] suggests that silylenes of this type may be superior to fc[(NC6H3-2,6-iPr2)2Si] in terms of ambiphilicity. [ABSTRACT FROM AUTHOR] |
