| Autor: |
Joekar, Delara, Hiscock, Lana K., Dawe, Louise N. |
| Předmět: |
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| Zdroj: |
Acta Crystallographica Section E: Crystallographic Communications; Oct2023, Vol. 79 Issue 10, p926-930, 11p |
| Abstrakt: |
A key step towards utilizing polynuclear metal-based systems in magnetic device applications involves the careful design of ligands. This strategic planning aims to produce metal assemblies that exhibit some kind of 'switch' mechanism. Towards this end, a ligand that incorporates a redox-active functional group (ferrocene) is reported. This communication presents the multi-step synthesis, characterization (¹H and 13C NMR), and structural analysis (single-crystal X-ray diffraction and Hirshfeld surface analysis) of 3-ferrocenyl-1-(pyridin-2-yl)-1Hpyrazol-5-amine, [Fe(C5H5)(C13H11N4)]. Supramolecular features, including π--π stacking and hydrogen bonding are quantified, while a database search reveals the unique combination of molecular moieties, which offer future opportunities for studies to involve simultaneous Lewis acid and base coordination. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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