Autor: |
Kovanova, M. A., Tikhomirova, T. V., Sakhapov, I. F., Gafurov, Z. N., Yakhvarov, D. G., Vashurin, A. S. |
Předmět: |
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Zdroj: |
Russian Journal of Electrochemistry; Sep2023, Vol. 59 Issue 9, p646-650, 5p |
Abstrakt: |
The electrochemical behavior of tetra-4-[4-(2,4,5-trichlorophenoxy)]phthalocyaninates of cobalt(II) (CoPc) and copper(II) (CuPc) in N,N-dimethylformamide with 0.1 M nBu4NBF4 as a supporting electrolyte is studied by cyclic voltammetry. It is shown experimentally that both metal complexes are capable of irreversible reduction. In this case, the reverse CV-scan for CoPc demonstrates an oxidation peak which is absent in the anodic scan and corresponds to the cathodic reaction product. The metal complexes themselves are not oxidized under these conditions. [ABSTRACT FROM AUTHOR] |
Databáze: |
Complementary Index |
Externí odkaz: |
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