| Autor: |
Bołt, Małgorzata, Mermela, Aleksandra, Żak, Patrycja |
| Předmět: |
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| Zdroj: |
Chemical Communications; 10/4/2023, Vol. 59 Issue 77, p11548-11551, 4p |
| Abstrakt: |
A new catalytic system, based on an octacarbonyl dicobalt(0) complex and bulky ligand, providing a route to α-vinylgermanes is described. The proposed method can be effectively used for Markovnikov-selective hydrogermylation of a number of terminal and internal alkynes. It has been proved that analogous catalytic systems containing less sterically demanding ligands cannot serve as selective catalysts in this transformation. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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