| Abstrakt: |
Nitrogen (N)-containing compounds have a significant impact on the optical and toxicological properties of aerosols. 1,2,4-Trioxolanes, known as secondary ozonides (SOZs), key products from the ozonolysis of biogenic terpenoids, are readily taken up into atmospheric aerosols and act as oxidants, potentially interacting with amines in the atmosphere. In the present work, we carefully investigated the component of the particles produced by the ozonolysis of β-caryophyllene (β-C) in the presence of ethylamine (EA), methylamine (MA), dimethylamine (DMA) or ammonia. The mass spectrometric results show that SOZ is the dominant product from the ozonolysis of β-C. It readily reacts with EA and MA but has inert reactivities toward DMA and ammonia. Similar experimental results were achieved with α-humulene (α-H), an isomer of β-C, was used in place of β-C. Additionally, D2O and H218O solvents were used for the characterization of products. The results revealed an intriguing phenomenon that the products from β-C SOZ and α-H SOZ reacting with the same amine (EA or MA) possessed different functional groups, despite the fact that they are isomerized species with the identical chemical structure (1,2,4-trioxolane). That indicates the chemical conformation of SOZs has a strong influence on how they react with amines. For the first time, SOZs derived from β-C and α-H reacting with amines is reported in this study, that may represent a hitherto unrecognized source of N-containing compounds production in atmospheric aerosols. [ABSTRACT FROM AUTHOR] |
