BaAl1.4Si0.6O3.4N0.6:Eu2+ green phosphors’ application for improving luminous performance.

Autor: My Hanh Nguyen Thi, Nguyen Le Thai, Thuc Minh Bui, Tam Nguyen Kieu
Předmět:
Zdroj: International Journal of Electrical & Computer Engineering (2088-8708); Oct2023, Vol. 13 Issue 5, p4958-4965, 8p
Abstrakt: The molten salt synthesis (MSS) method was used to effectively prepare green phosphors BaAl1.4Si0.6O3.4N0.6:Eu2+ (or BSON:Eu2+) via one homogeneous sphere-like morphology utilizing NaNO3 in the form of the reacting agent. The phosphors produced one wide stimulation spectrum between 250 and 460 nm, as well as a significant green emission has a maximum point at 510 nm owing to the 4f65d¹-4f7 (8S7/2) shifts for Eu2+ ions. With illumination under 365 as well as 450 nm, the ideal discharge strengths for the specimen prepared utilizing melted salt would receive a boost of 17% and 13%, surpassing the specimen prepared utilizing the traditional solid-state reaction (SSR) approach. The abatement of concentration for the ions of Eu2+ from BSON:Eu2+ is 5 mol%. In addition, the interactivity of dipole-dipole would be the cause of said abatement. Heat abatement would be studied utilizing the formation coordinate method with abatement temperature reaching ∼200 oC. Elemental mapping as well as power-dispersing X-ray spectroscopy (EDS) spectra demonstrated that the expected BaAl1.4Si0.6O3.4N0.6:Eu2+ materials were formed. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index