Pyrrolocoumarins. 1. Synthesis and Spectroscopic Investigation of 7-Oxo- and 1,2,7-Trioxo-1,2-dihydropyrano-[3,2-e]indole and Their Derivatives.

Autor: Khoshtariya, T. E., Kurkovskaya, L. N., Bochoidze, L. T., Batsikadze, K. T., Mirziashvili, N. T., Abesadze, I. G., Sikharulidze, M. I., Turabelidze, V. G., Ananiashvili, V. O., Dzhashi, T. O., Maisuradze, M. G.
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds; Feb2005, Vol. 41 Issue 2, p208-215, 8p
Abstrakt: A preparative route is proposed for the synthesis of the novel heterocyclic systems 7-oxo- and 1,2,7-trioxo-1,2-dihydropyrano[3,2-e]indole using classical Fischer and Sandmeyer methods respectively. We have studied various conditions for cyclization of the starting coumarin 6-isonitrosoacetamide and the methyl or ethyl pyruvate 6-coumarinylhydrazones. The syn- and anti-form ratio of the latter and the structure of all of the synthesized compounds were determined using spectroscopic data analysis. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index