| Autor: |
Bao, Yide-Rigen, Duan, Yu, Na, Yong |
| Zdroj: |
Journal of Materials Chemistry A; 9/21/2023, Vol. 11 Issue 35, p18668-18671, 4p |
| Abstrakt: |
The conversion of 5-hydroxymethylfurfural (HMF) into value-added chemicals represents a sustainable bridge toward renewable carbon sources. Inspired by the function of the manganese framework in the active site of the oxygen evolving complex (OEC) in natural photosynthesis, Ni1Mn5-LDH was developed as the most efficient Ni-based electrocatalyst for HMF oxidation to FDCA among the reported materials. A faradaic efficiency of 97% was achieved at 1.4 V (vs. RHE), resulting in FDCA production in a yield of 94.72%. An insight into the reaction pathway indicated that the oxidation of the CH2OH group to the CHO group was the rate-limiting step during HMF oxidation. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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