| Autor: |
Umirova, Gulnora A., Turaev, Khayit Kh., Alimnazarov, Bekmurod Kh., Kasimov, Sherzod A., Djalilov, Abdulakhat T., Ibragimov, Bakhtiyar T., Ashurov, Jamshid M. |
| Předmět: |
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| Zdroj: |
Acta Crystallographica Section E: Crystallographic Communications; Aug2023, Vol. 79 Issue 9, p856-861, 10p |
| Abstrakt: |
The reaction of 8-aminoquinoline, zinc chloride and hydrochloric acid in ethanol yielded the title salt, (C9H10N2)[ZnCl4], which consists of a planar 8-azaniumylquinolinium dication and a tetrahedral tetrachlorozincate dianion. The 8-aminoquinoline moiety is protonated at both the amino and the ring N atoms. In the crystal, the cations and anions are connected by intermolecular N--H...Cl and C--H...Cl hydrogen bonds, forming sheets parallel to (001). Adjacent sheets are linked through π-π interactions involving the pyridine and arene rings of the 8-azaniumylquinolinium dication. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H...Cl (48.1%), H...H (19.9%), H...C/C...H (14.3%) (involving the cations) and H...Cl (82.6%) (involving the anions) interactions. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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