A New Ultrafine Luminescent La 2 O 3 :Eu 3+ Aerogel.

Autor: García Ramírez, Víctor M., García Murillo, Antonieta, Carrillo Romo, Felipe de J., Alvarez González, Rosa I., Madrigal Bujaidar, Eduardo
Předmět:
Zdroj: Gels (2310-2861); Aug2023, Vol. 9 Issue 8, p615, 11p
Abstrakt: This paper reports on the synthesis and characterization of La2O3:Eu3+ luminescent aerogels fabricated by the sol–gel method and the supercritical drying technique. The % mol concentration of the Eu3+ ion was varied to study the effects on the luminescent properties of the aerogels. XRD and TEM analysis showed that the La2O3:Eu3+ aerogels exhibited a semi-crystalline behavior regardless of whether the concentration of europium was increased. SEM micrographs revealed a porous structure in the aerogels, which were composed of quasi-spherical nanoparticles that were interconnected and formed coral-shaped agglomerates. Photoluminescence spectroscopy characterization showed that the aerogels had an infrared emission located at λ = 793 nm, and the maximum photoluminescence emission intensity was observed for the aerogel with 50% Eu3+. The results demonstrate that, without heat treatment, it is possible to manufacture luminescent aerogels of rare-earth oxides that can be used in opto-electronic devices. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index