Features of the 1,3,5-Trioxane Stabilization Process.

Autor: Leshina, M. N., Mazlov, A. M., Kornienko, P. V., Shirshin, K. V., Vidyaeva, T. I., Solodukhin, A. A., Ilyash, A. Ya.
Zdroj: Polymer Science -- Series D; Jun2023, Vol. 16 Issue 2, p322-326, 5p
Abstrakt: It has been shown that, at a temperature of 75°C, 1,3,5-trioxane obtained by the liquid-phase method in the presence of a homogeneous catalyst partially decomposes with the formation of free formaldehyde, paraformaldehyde, and formic acid. A number of stabilizers for the thermal-oxidative degradation of 1,3,5-trioxane have been proposed and their effectiveness has been compared. The most effective additives were selected and their concentrations were determined, which provide the minimum amount of by-product formation under the indicated conditions. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index