A squaramide cage capable of binding and extracting H2PO4− and HP2O73− in highly polar protic media.

Autor: Yang, Ju Ho, Kim, Sung Kuk
Předmět:
Zdroj: Chemical Communications; 8/25/2023, Vol. 59 Issue 66, p9988-9991, 4p
Abstrakt: A novel squaramide cage (2) binds H2PO4 and HP2O73− with high selectivity and affinity in a highly polar protic solvent system. Receptor 2 is also able to extract these hydrophilic anions into a chloroform phase from water. The X-ray crystal structure demonstrated that compound 2 forms a complex with H2PO4 with 1 : 1 stoichiometry in the solid state. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index