| Autor: |
Khajone, Vijay Baburao, Raut, Subodh Uttamrao, Deshmukh, Shubham Avinash, Bhansali, Karan Jeevanlal, Balinge, Kamlesh Rudreshwar, Muskawar, Prashant Narayan, Bhagat, Pundlik Rambhau |
| Zdroj: |
Biomass Conversion & Biorefinery; Jul2023, Vol. 13 Issue 10, p9107-9117, 11p |
| Abstrakt: |
The protocol presents conversion of levulinic acid (LA) to γ-valerolactone (GVL), using polymer-supported carboxyl functionalized Zn–porphyrin (PSCFZnPP) as a photocatalyst under visible light at ambient conditions. The formation of GVL was achieved using 2-propanol as a hydrogen source over PSCFZnPP photocatalyst in a homemade photoreactor under 12-W LED light. The formation of GVL was achieved with 72% yield by transfer hydrogenation in 16 h at room temperature and confirmed by 1H-NMR and 13C-NMR at various intervals. The transformation of LA was confirmed by the presence of CH multiplet in 1H-NMR and deshielding of CH3 protons in GVL around 1 ppm, after 16 h with disappearance of OH of the substrate. It was further evidenced by the disappearance of ketonic carbonyl C peak height and reduction of LA in 13C-NMR. Finally, PSCFZnPP exhibited reusability for five times using optimized conditions without significant changes in the yield and structure. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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