Acylation of Electron-Poor Alkenyl Sulfoxides: Diverse Transformations for the Synthesis of Polysubstituted Phenols and Functionalized Carbocycles.

Autor: Li, Xiaoyu, Zhang, Qianyun, Xie, Yuanyuan, Zhou, Hongwei
Předmět:
Zdroj: Synthesis; Sep2023, Vol. 55 Issue 17, p2674-2682, 9p
Abstrakt: HRMS (ESI-TOF): I m i / I z i [M + Na] SP + sp calcd for C SB 14 sb H SB 14 sb ClFNaO SB 3 sb S SP + sp : 339.0228; found: 339.0236. Keywords: alkenyl sulfoxides; sulfonium ions; functionalized carbocycles; polysubstituted phenols; aromatization EN alkenyl sulfoxides sulfonium ions functionalized carbocycles polysubstituted phenols aromatization 2674 2682 9 08/17/23 20230901 NES 230901 Graph Sulfonium ions might be the most diverse intermediates in the area of organosulfur chemistry, involved in numerous reactions such as the Pummerer rearrangement, [1] Swern oxidation [2] and sulfur ylide formation. HRMS (ESI-TOF): I m i / I z i [M + Na] SP + sp calcd for C SB 14 sb H SB 14 sb NaO SB 3 sb S SP + sp : 285.0556; found: 285.0562. HRMS (ESI-TOF): I m i / I z i [M + Na] SP + sp calcd for C SB 14 sb H SB 15 sb ClNaO SB 3 sb S SP + sp : 321.0323; found: 321.0323. [Extracted from the article]
Databáze: Complementary Index