Investigation into the Hydration Behavior of K2CO3 Packed Beds: An NMR Study.

Autor: Raemaekers, Tim, Donkers, Pim, Huinink, Henk
Předmět:
Zdroj: Transport in Porous Media; Sep2023, Vol. 149 Issue 3, p817-835, 19p
Abstrakt: K2CO3 is seen as a promising heat storage material, available for applications in the domestic sector. For practical purposes, the material is hereby often employed in a packed bed containing millimeter-sized particles. To gain more insight into the hydration behavior of these packed beds, quantitative NMR measurements, capable of following the in-situ hydration behavior, are presented for the first time. It is found that hydration behavior varies significantly, depending on the specific hydration conditions that are chosen. At low airflows hydration is found to proceed via a hydration front, while higher airflows cause the hydration front to widen. Since an increase in flow rate coincided with an increase in the supplied water vapor, hydration is eventually found to proceed in a uniform manner. A comparison between TGA and NMR measurements shows that the overall packed bed hydration kinetics hereby transition to the reaction kinetics of single K2CO3 particles. Article Highlights: NMR is used for the first time to quantitatively study K2CO3 packed bed hydration Packed bed hydration behavior is found to be front-like for low flow rate; high flow rate results in uniform hydration For sufficiently high flow rates hydration kinetics are limited at single grain level [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index