Kinetics of Formation of Metallic Aluminum upon Thermal and Photolytic Decomposition of Aluminum Trihydride and Trideuteride as Probed by NMR.

Autor: Tarasov, V. P., Muravlev, Yu. B., Bakum, S. I., Novikov, A. V.
Předmět:
Zdroj: Doklady Physical Chemistry; Dec2003, Vol. 393 Issue 4-6, p353-356, 4p
Abstrakt: Discusses the kinetics of formation of metallic aluminum upon thermal and photolytic decomposition of aluminum trihydride and trideuteride as probed by NMR. Formation of the only binary hydride by aluminum and hydrogen; Domination of photolysis by aluminum nucleation; Prevalence of nucleus growth in thermolysis; Formation and growth of the metallic aluminum phase upon decomposition of aluminum trihydride; Thermolysis and photolysis of aluminum trihydride and trideuteride.
Databáze: Complementary Index