Study of Hydrolysis of O-Alkyl Methylphosphonofluoridates by Quantum-Chemical Methods: The Conformational Aspect.

Autor: Strukov, O. G., Petrunin, V. A., Vlasova, Z. V., Zavalishina, I. V., Utkina, S. V., Fadeev, V. N., Drozd, G. I., Myasoedov, B. F.
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Zdroj: Doklady Physical Chemistry; Nov2003, Vol. 393 Issue 1-3, p297-302, 6p
Abstrakt: Discusses the study of hydrolysis of o-Alkyl methylphosphonofluoridates by quantum chemical methods. Demonstration that, in this reaction, as well as in other reactions of nucleophilic substitution at the phosphorus atom, intermediate five-coordinate structures are formed; in some cases, the existence of these intermediates was supported by experiments.
Databáze: Complementary Index