Synthesis of α‐Substituted N ‐Aryl Acrylamide Derivatives Through Baylis–Hillman Reaction.

Autor:	Guo, Wei, Wu, Weiwei, Fan, Ningjuan, Wu, Zhengang, Xia, Chizhong
Předmět:	AROMATIC compounds ALDEHYDES ACRYLAMIDE CHEMICAL reactions
Zdroj:	Synthetic Communications; 2005, Vol. 35 Issue 9, p1239-1251, 13p, 4 Diagrams, 3 Charts
Abstrakt:	N -aryl acrylamides were found to be the more activated Michael acceptor forBaylis–Hillman reaction than acrylamides and N -alkyl acrylamides. Treatment of N -aryl acrylamides with aromatic aldehydes in the presence of DABCO (1,4-diazabicyclo[2·2·2]octane) afforded the desired Baylis–Hillman products, a-substituted acrylamide derivatives, which have important applications as novel radical polymerization monomers and biologically important reagents. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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