| Autor: |
Reiter, L. G., Bobyr, S. A., Shubina, T. E., Rodionov, V. N. |
| Předmět: |
|
| Zdroj: |
Theoretical & Experimental Chemistry; Jan2005, Vol. 41 Issue 1, p7-12, 6p |
| Abstrakt: |
The kinetics of the fac?mer isomerization of cobalt(III) trisaminoethoxide were studied. The acceleration of the reaction with decrease of the pH of the solution is explained by the formation of a reactive monoprotonated form of the complex. The direction of isomerization agrees with quantum-chemical calculations performed at the B3LYP/6-31G** level. The rate constants and activation parameters of the process were obtained. The mechanism of isomerization is discussed. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
