Reactions of 2-(2-Furyl)-1,3-dioxacycloalkanes with Triethylsilane.

Autor: Chanysheva, K. V., Tokunova, E. F., Khusainov, M. A., Khlebnikova, T. D., Shakirova, F. M., Grishin, S. A., Kantor, E. A.
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Zdroj: Russian Journal of Organic Chemistry; Jun2003, Vol. 39 Issue 6, p903-904, 2p
Abstrakt: The article reports on the chemical reactions of dioxacycloalkanes compounds with triethylsilanes. 1,3-Dioxacycloalkanes react with triethylsilane in the presence of various catalysts furnishing products of heterocycle cleavage at the carbon-oxygen single bond of the acetal site, alkoxy (triethylsiloxy)alkanes [1, 2] possessing high biological activity. The article also reports on procedure for preparation of &b.alpha;-triethylsiloxy-&b.omega;- furfuryloxyalkanes. The article includes details of reaction processes.
Databáze: Complementary Index