Synthesis of Allyl 2-Dialkylamino-4-pentenoates and Their Analogs via Stevens Rearrangement.

Autor: Babakhanyan, A. V., Shakhbazyan, L. G., Grigoryan, Dzh. V., Kocharyan, S. T.
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Zdroj: Russian Journal of Organic Chemistry; Sep2003, Vol. 39 Issue 9, p1227-1230, 4p
Abstrakt: Stevens rearrangement of ammonium salts containing an allyloxycarbonylmethyl group in benzene in the presence of sodium phenoxide yields allyl 2-dialkylamino-4-pentenoates. The rearrangement in the presence of sodium methoxide is accompanied by transesterification to afford methyl 2-dialkylamino-4-pentenoates. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index