| Autor: |
Al'fonsov, V. A., Andreeva, O. V., Bakaleinik, G. A., Beskrovnyi, D. V., Gubaidullin, A. T., Kataev, V. E., Kovylyaeva, G. I., Konovalov, A. I., Korochkina, M. G., Latypov, Sh. K., Litvinov, I. A., Musin, R. Z., Strobykina, I. Yu. |
| Předmět: |
|
| Zdroj: |
Russian Journal of General Chemistry; Jul2003, Vol. 73 Issue 7, p1119-1129, 11p |
| Abstrakt: |
Esterification with alcohols and diols of (4α,8β,13β)-13-methyl-16-oxo-17-norkaurane-18-carboxylic acid chloride prepared by treatment of the acid (isosteviol) with thionyl chloride yields the corresponding esters. The molecular and crystal structures of a series of esters were determined by single crystal X-ray diffraction. The diethylene glycol diester in the crystal has a tweezer structure with an intramolecular cavity. The supramolecular structure of some isosteviol derivatives in the crystal is characterized by alternation of lipophilic and hydrophilic regions. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
