| Autor: |
Yarosh, O. G., Zhilitskaya, L. V., Yarosh, N. K., Istomina, E. E., Albanov, A. I., Chuvashev, Yu. A., Voronkov, M. G. |
| Předmět: |
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| Zdroj: |
Russian Journal of General Chemistry; Oct2004, Vol. 74 Issue 10, p1496-1500, 5p |
| Abstrakt: |
Two novel silicon-containing acetylenic synthons, 1-[dimethyl(ethynyl)silyl]-2-[ethynyl(methyl)-(vinyl)silyl]ethyne and bis[(ethynyldimethylsilyl)ethynyl](methyl)vinylsilane, were obtained by the reaction of diethynyl(methyl)vinylsilane with ethylmagnesium bromide and ethynylfluorodimethylsilane. The reaction of magnesium derivatives of the products and diethynyl(methyl)vinylsilane with organylhalosilanes gave macrocyclic polyunsaturated silahydrocarbons containing numerous endo- and exocyclic miltiple bonds. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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