Tandem Rearrangement-heterocyclization in the Reactions of Tetrafluorobenzobarrelene with Hetarenesulfenyl Chlorides.

Autor: Borisov, A. V., Borisova, G. N., Nikonova, Yu. A., Osmanov, V. K., Matsulevich, Zh. V.
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds; Sep2003, Vol. 39 Issue 9, p1261-1262, 2p
Abstrakt: Investigates the reaction of diene with hetarenesulfenyl chlorides, containing a potentially nucleophilic nitrogen atom in the hetaryl fragment, in an effort to develop a new approach for synthesis of sulfur heterocycles. Use of a system containing lithium perchlorate and nitromethane to induce the cycloaddition of 1-phenyl-5-tetrazolesulfenyl chloride and 1,3-benzo-2-thiazolesulfenyl chloride to diene; Ring closure; Wagner-Meerwein rearrangement; General method for the sulfenylation of diene.
Databáze: Complementary Index