| Autor: |
Münzfeld, Luca, Hauser, Adrian, Gamer, Michael T., Roesky, Peter W. |
| Předmět: |
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| Zdroj: |
Chemical Communications; 7/28/2023, Vol. 59 Issue 59, p9070-9073, 4p |
| Abstrakt: |
The synthesis of the first half-sandwich complexes based on the cyclononatetraenyl (Cnt = C9H9−) ligand ([LnIII(η9-Cnt)(η3-BH4)2(thf)] (Ln = La, Ce)) is reported. The title compounds were obtained from the reaction of [Ln(BH4)3(thf)3] and [K(Cnt)]. Further solvation of [LnIII(η9-Cnt)(η3-BH4)2(thf)] with tetrahydrofuran (THF) resulted in a reversible decoordination of the Cnt ring and the formation of the ionic species [LnIII(η3-BH4)2(thf)5][Cnt]. Removal of THF from [LaIII(η9-Cnt)(η3-BH4)2(thf)] gave the polymeric compound [LaIII(μ-η2:η2-BH4)2(η3-BH4)(η9-Cnt)]n. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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