Synthesis and Properties of Methylene-Bridged [6]Cyclo-2,6-naphthylene.

Autor: Kai, Nobushige, Kono, Hideya, Yagi, Akiko, Itami, Kenichiro
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Zdroj: Synlett; Jul2023, Vol. 34 Issue 12, p1433-1436, 4p
Abstrakt: Keywords: cycloparaphenylenes; cyclonaphthylenes; molecular nanocarbons; carbon nanobelts; methylene-bridged nanobelts; prism[6]arenes EN cycloparaphenylenes cyclonaphthylenes molecular nanocarbons carbon nanobelts methylene-bridged nanobelts prism[6]arenes 1433 1436 4 07/11/23 20230725 NES 230725 Graph Aromatic nanobelts are molecules that have attracted a great deal of attention in recent chemistry. [6]MCN was extracted from the reaction mixture by using a large amount of toluene, in which [6]MCN is slightly soluble, affording pure [6]MCN after two cycles of precipitation with 1:2 toluene-hexane. 2014, 50: 5774 24 Li, Y. Segawa, Y. Yagi, A. Itami, K. J. Am. Chem. Soc. 2020, 142: 12850 25 Yagi, A. Segawa, Y. Itami, K. J. Am. Chem. Soc. 2012, 134: 2962 26 Sun, Z. Sarkar, P. Suenaga, T. Sato, S. Isobe, H. Angew. Int. Ed. 2015, 54: 12800 27 Okada, K. Yagi, A. Segawa, Y. Itami, K. Chem. Sci. 2017, 8: 661 28 Jia, H. Gao, Y. Huang, Q. Cui, S. Du, P. Chem. Commun. [Extracted from the article]
Databáze: Complementary Index