| Autor: |
Vasilev, Aleksey A., Baluschev, Stanislav, Ilieva, Sonia, Cheshmedzhieva, Diana |
| Předmět: |
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| Zdroj: |
Photochem; Jun2023, Vol. 3 Issue 2, p301-312, 12p |
| Abstrakt: |
The potential of E–Z photoisomerization in molecular organic light-to-thermal conversion and storage in an E–styryl merocyanine system was studied in a polar acidic medium. A photoswitchable styryl merocyanine dye (E)-2-(2-(2-hydroxynaphthalen-1-yl)vinyl)-3,5-dimethylbenzo[d]thiazol-3-ium iodide was synthesized for the first time. The reversible E–Z photoisomerisation of the dye was investigated using UV-Vis spectroscopy and DFT calculations. E–Z isomerization was induced through the use of visible light irradiation (λ = 450 nm). The obtained experimental and theoretical results confirm the applicability of the Z and E isomers for proton-triggered light harvesting. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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