| Autor: |
Dohnal, Petr, Jusko, Pavol, Jiménez-Redondo, Miguel, Caselli, Paola |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 6/28/2023, Vol. 158 Issue 24, p1-8, 8p |
| Abstrakt: |
The experimental determination of the reaction rate coefficients for production and destruction of HCN+ and HNC+ in collision with H2 is presented. A variable-temperature, 22-pole radio frequency ion trap was used to study the reactions in the temperature range 17–250 K. The obtained rate coefficients for the reaction of CN+ and HCN+ with H2 are close to the collisional (Langevin) value, whereas that for the reaction of HNC+ with H2 is quickly decreasing with increasing temperature. The product branching ratios for the reaction of CN+ with H2 are also reported and show a notable decrease of the HNC+ product with respect to the HCN+ product with increasing temperature. These measurements have consequences for current astrochemical models of cyanide chemistry, in particular, for the HCNH+ cation. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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