| Autor: |
Kagami, Kentaro, Liang, Xueying, Ishibashi, Nanako, Ohrui, Sayaka, Tayu, Masanori, Saito, Nozomi |
| Předmět: |
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| Zdroj: |
Chemical Communications; 7/7/2023, Vol. 59 Issue 53, p8274-8277, 4p |
| Abstrakt: |
The first synthesis of N-(acyloxy)ynamides was realized through the coupling of N-(acyloxy)amides and hypervalent alkynyliodane under mild conditions. This reaction probably involves biradical species ("C2") generation and radical processes. Furthermore, we also demonstrated that N-(acyloxy)ynamide could be transformed into a N-sulfonylimidate derivative by a copper catalyst. This study provides new building blocks for synthetic organic chemistry reactions and improves understanding of the chemical reactivity of "C2". [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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