Hydroarylation of alkynes via dual ortho-C–H functionalization of diaryl amines on a dicopper(I,I) platform.

Autor: Pal, Nilay Kumar, Patra, Moumita, Pandey, Prabhakar K., Bera, Jitendra K.
Předmět:
Zdroj: Chemical Communications; 7/4/2023, Vol. 59 Issue 52, p8079-8082, 4p
Abstrakt: A pyridine and morpholine-functionalized dicopper(I , I)-NHC complex (1) features both terminal and bridging coordination modes of NHC within the same molecule, and catalyzes dual ortho-C–H functionalization of diaryl amines for the hydroarylation of alkynes. A bimetallic construct in catalyst 1 allows sequential activation of ortho-C–H bonds of two aryl units to furnish a wide variety of 9,10-dihydroacridine derivatives without the explicit use of a directing group. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index