| Autor: |
Redko, A. V., Tamarkina, Yu. V., Redko, A. M., Frolova, I. B., Kucherenko, V. A. |
| Předmět: |
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| Zdroj: |
Issues of Chemistry & Chemical Technology / Voprosy Khimii & Khimicheskoi Tekhnologii; May2023, Issue 2, p127-136, 10p |
| Abstrakt: |
The purpose of the work is to evaluate the influence of topochemical oxidation (H2O2, HNO3) of carbon prepared by alkali activation of coal on porosity and ability to adsorb 4-chlorophenol (CPh), Pb(II) cations and iodine. Carbons were oxidized at the reactant/carbon ratio of 1:1 (mol/mol, 25°C, 24 h). Based on nitrogen adsorption-desorption isotherms, the volumes and specific surfaces of ultramicro- (Sumi), supermicro- (Ssmi) and other pores were evaluated. Kinetics and adsorption isotherms (25°C) of CPh and Pb(II) were characterized; adsorption capacities of CPh, Pb(II) and I 2 were determined. The H2O2-assisted modification was found to significantly increase Sumi (from 615 to 829 m²/g), but decrease Ssmi(from 515 to 494 m²/g). The HNO3-assisted modification slightly increases Sumi (from 615 to 651 m²/g), does not change Ssmi, but forms mesopores. The CPh adsorption is best approximated by the second-order kinetics, and isotherms are well fitted with the use of the Langmuir model. The H2O2 treatment increases the CPh capacity from 314 to 389 mg/g; and the HNO3 modification significantly decreases the CPh capacity (to 189 mg/g). Modifications reduce the iodine capacity by 1.11 times (H2O2) and 2.33 times (HNO3). The Pb(II) absorption was established to describe by the second-order kinetics equation; the adsorption isotherms obey Langmuir (R²≥0.986) and Freundlich (R²≥0.984) models. The Pb(II) capacity slightly increases after H2O2-assisted modification (from 87 to 95 mg/g), but increases sharply (from 87 to 298 mg/g) after HNO3-assisted treatment because of significant increasing OH-acidic groups concentration. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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