Improvement of Heat Dissipation in Ag/Ni Substrates for Testing Cu-TiO 2 /TiO 2 -Modified Filters Using SERS Spectroscopy.

Autor: Bandarenka, Hanna, Burko, Aliaksandr, Girel, Kseniya, Laputsko, Diana, Orel, Elizaveta, Mizgailo, Anna, Sharopov, Utkirjon, Podelinska, Alise, Shapel, Uladzislau, Pankratov, Vladimir, Piskunov, Sergei, Bocharov, Dmitry
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Zdroj: Crystals (2073-4352); May2023, Vol. 13 Issue 5, p749, 12p
Abstrakt: Surface-enhanced Raman scattering (SERS) spectroscopy is used to investigate a composition of wash swabs from the Cu-TiO2/TiO2-modified filters with disinfecting ability. Macroporous Si chips coated with conformal 800 nm thick Ni layer and Ag particles (Ag/Ni) are engineered to act as SERS-active substrates. Such substrates are characterized by a moderate reflection band in the visible range and provide an improved heat dissipation from contaminants in wash swabs during SERS study. This prevents thermal-induced destruction of analyzing media for reliable assessment of its composition. The anatase Cu-TiO2 and TiO2 nanoparticles are synthesized using the sol-gel method and characterized via Raman spectroscopy and X-ray diffractometry. The filters are modified with Cu-TiO2/TiO2 nanoparticles and embedded in three-valve facial masks that are worn by a volunteer to breathe for 4 h. Comparative SERS analysis of the filters shows that they slightly destroy chemical bonds in the molecules constituting airborne contaminations upon ceiling day lights, which can be associated with Cu-TiO2 photocatalytic activity. The filters additionally exposed to near-ultraviolet light prominently decrease the intensity of Raman signatures of airborne contaminant due to the presence of pure TiO2. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index