A Strong‐Acid‐Resistant [Th6] Cluster‐Based Framework for Effectively and Size‐Selectively Catalyzing Reductive Amination of Aldehydes with N,N‐Dimethylformamide.

Autor:	Tian, Xue‐Rui, Jiang, Zhi‐Yu, Hou, Sheng‐Li, Hu, Han‐Shi, Li, Jun, Zhao, Bin
Předmět:	AMINATION ALDEHYDES HETEROGENEOUS catalysis TERTIARY amines HETEROGENEOUS catalysts DENSITY functional theory
Zdroj:	Angewandte Chemie; 6/5/2023, Vol. 135 Issue 23, p1-9, 9p
Abstrakt:	Utilization of N,N‐dimethylformamide (DMF) as an amine source and reductant for synthesizing tertiary amines is a promising way to replace the substrates formaldehyde and dimethylamine, and it is desirable to seek porous acid‐resistant catalysts for heterogeneous catalysis of this reaction. Herein, a robust metal–organic framework (MOF) {[Th6O4(OH)4(H2O)6(BCP)3]⋅10 DMF}n (1) containing stacked nanocages with a diameter of 1.55 nm was constructed. Compound 1 can maintain its single‐crystal structure even kept in air at 400 °C for 3 h, and in DMF or water at 200 °C for 7 days. Density functional theory (DFT) calculations suggested that the high interaction energy between the [Th6O4(OH)4(H2O)6]12+ clusters and ligands was responsible for the excellent stability of 1. Catalytic investigations revealed that 1 can effectively and size‐selectively catalyze the reductive amination of aldehydes with DMF, and it can be reused at least five times without obvious loss in catalytic activity. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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