Evaluating the energy landscape of an out-of-equilibrium bistable [2]rotaxane containing monopyrrolotetrathiafulvalene.

Autor: Neumann, Mathias S., Smith, Amanda F., Jensen, Sofie K., Frederiksen, Rikke, Skavenborg, Mathias L., Jeppesen, Jan O.
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Zdroj: Chemical Communications; 5/25/2023, Vol. 59 Issue 42, p6335-6338, 4p
Abstrakt: The unique redox properties of monopyrrolotetrathiafulvalene can be used to induce directional movement in interlocked molecules. In this study, the kinetics for the directional movement of cyclobis(paraquat-p-phenylene) across the dioxidised monopyrrolotetrathiafulvalene in a [2]rotaxane is quantified by time-resolved 1H NMR spectroscopy. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index