| Autor: |
Perin, Gelson, Araujo, Daniela Rodrigues, Nobre, Patrick Carvalho, Lenardao, Eder João, Jacob, Raquel Guimarães, Silva, Marcio Santos, Roehrs, Juliano Alex |
| Předmět: |
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| Zdroj: |
PeerJ; 2018, Vol. 6, p1-15, 15p |
| Abstrakt: |
A green methodology to synthesize 2-organoselanyl-naphthalenes based on the reaction of alkynols with diaryl diselenides is described. The electrophilic species of selenium were generated in situ, by the oxidative cleavage of the Se–Se bond of diaryl diselenides by Oxone® using water as the solvent. The reactions proceeded efficiently under ultrasonic irradiation as an alternative energy source, using a range of alkynols and diorganyl diselenides as starting materials. Through this methodology, the corresponding 2-organoselanyl-naphthalenes were obtained in moderate to good yields (56–94%) and in short reaction times (0.25–2.3 h). [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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