Host‐guest Assembly Based on γ‐Cyclodextrin‐functionalized Multiwalled Carbon Nanotubes for Rutin Electrochemical Sensing.

Autor: Gomes dos Santos Neto, Antônio, de Matos Morawski, Franciele, Caroline Ferreira Santos, Ana, Quintino da Rocha, Cláudia, Batista de Lima, Roberto, Oliveira Fonseca Goulart, Marília, Costa dos Santos, Clenilton, Colmati, Flávio, Euzébio Goulart Santana, Antônio, Aurélio Suller Garcia, Marco, Atsushi Tanaka, Auro
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Zdroj: Electroanalysis; May2023, Vol. 35 Issue 5, p1-11, 11p
Abstrakt: Here, we report multiwalled carbon nanotubes (MWCNTs) functionalized with γ‐cyclodextrins (γCD) as a novel electrochemical strategy for Rutin determination, showing superior performance than β‐cyclodextrins (βCD) modified MWCNTs, suggesting an adequate environment for host‐guest interactions. Under optimized conditions, the sensor showed a linear range of 39–975 nmol L−1 and a limit of detection of 7 nmol L−1. When tested with quercetin, catechin, and caffeine, the platform presented high selectivity with an interference response <10 %. The method was employed to quantify Rutin in spiked pharmaceutical and herbal extracts, providing recovery of 93–98.4 %. Also, HPLC‐PDA confirmed the method's accuracy. [ABSTRACT FROM AUTHOR]
Databáze: Complementary Index
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