| Autor: |
G.-Simonian, Nicolas, Guérinot, Amandine, Cossy, Janine |
| Předmět: |
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| Zdroj: |
Synthesis; Jun2023, Vol. 55 Issue 11, p1616-1641, 26p |
| Abstrakt: |
(Het)aryl migration has emerged as a key synthetic tool and has particularly been exploited for the synthesis of α-aryl amides. This method overcomes the existing α-arylation methods, which are not always compatible with the introduction of (het)aryl groups possessing bulky or electrophilic substituents. This review focuses on SO2-extrusive (het)aryl migration in the frame of α-aryl amide synthesis. Anion- and radical-mediated transformations are reported, including the synthesis of polycyclic compounds through cascade reactions. 1 Introduction 2 Anionic Aryl Migration 3 Radical Aryl Migration 4 Conclusion [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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