| Autor: |
Wang, Zhan-Yong, Yang, Ting, Wang, Kai-Kai, Liu, Dong-Fang, Ma, Xueji, Wang, Nan, Liu, Hong, Sun, Aili, Liu, Hongxin |
| Předmět: |
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| Zdroj: |
Green Chemistry; 4/21/2023, Vol. 25 Issue 8, p3040-3045, 6p |
| Abstrakt: |
A water-promoted DABCO-organocatalyzed hydrodecarboxylation of conjugated carboxylic acids has been developed, providing the corresponding decarboxylation products in good to excellent yields. This metal-, photocatalyst-, and oxidant-free protocol features high functional group tolerance, wide substrate scope, gram-scale synthesis, and operational simplicity under open air conditions at room temperature. A trace amount of water as the hydrogen source for the successful conversion and the origin of the chemoselectivity are demonstrated through a series of control experiments. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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