Dibenzyl-(1 S *,2 S *)-2,3-dihydro-1 H -indene-1,2-dicarboxylate.

Autor:	Olivieri, Diego, Tarroni, Riccardo, Carfagna, Carla
Předmět:	BENZYL alcohol CARBON monoxide ALCOHOL oxidation SUCCINIC acid HOMOGENEOUS catalysis SUCCINATES
Zdroj:	Molbank; Mar2023, Vol. 2023 Issue 1, pM1586, 5p
Abstrakt:	The synthesis of dibenzyl-(1S*,2S*)-2,3-dihydro-1H-indene-1,2-dicarboxylate has been realized through a diastereospecific bis-alkoxycarbonylation reaction, which starts from the cheap and easily available 1H-indene, benzyl alcohol, and carbon monoxide. The catalyst is formed in situ by mixing Pd(TFA)2, the ligand N2,N3-bis(2,6-dimethylphenyl)butane-2,3-diimine, p-benzoquinone is used as an oxidant, and benzyl alcohol acts both as a nucleophile and as the main solvent. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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