| Autor: |
Valencia, Isabel, Sucunza, David, García-García, Patricia, Pérez-Redondo, Adrián, Vaquero, Juan J. |
| Předmět: |
|
| Zdroj: |
Synthesis; Apr2023, Vol. 55 Issue 8, p1260-1266, 7p |
| Abstrakt: |
Treatment of various vinylbenzopyridines with allyl(dichloro)borane affords five-membered organoborate heterocycles via a metal-free carboboration. The reaction between these organoborates and Grignard reagents increases the number of derivatives belonging to this novel family of four-coordinate organoboron compounds. Some of them were used as reagents in phenylations and methylations in moderate to high yields under standard palladium-catalyzed cross-coupling reaction conditions. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
|
