| Autor: |
Kumaki, Fumitoshi, Nagasaka, Masanari, Fukaya, Ryo, Okano, Yasuaki, Yamashita, Shohei, Nozawa, Shunsuke, Adachi, Shin-ichi, Adachi, Jun-ichi |
| Předmět: |
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| Zdroj: |
Journal of Chemical Physics; 3/14/2023, Vol. 158 Issue 10, p1-7, 7p |
| Abstrakt: |
Operando time-resolved soft x-ray absorption spectroscopy (TR-SXAS) is an effective method to reveal the photochemical processes of metal complexes in solutions. In this study, we have developed the TR-SXAS measurement system for observing various photochemical reactions in solutions by the combination of laser pump pulses with soft x-ray probe pulses from the synchrotron radiation. For the evaluation of the developed TR-SXAS system, we have measured nitrogen K-edge x-ray absorption spectroscopy (XAS) spectra of aqueous iron phenanthroline solutions during a photoinduced spin transition process. The decay process of the high spin state to the low spin state in the iron complex has been obtained from the ligand side by N K-edge XAS, and the time constant is close to that obtained from the central metal side by time-resolved Fe K-edge XAS in the previous studies. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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