| Autor: |
Miranda Jr., P., Mercuri, L.P., Matos, J.R., Máduar, M.F., Zukerman-Schpector, J. |
| Předmět: |
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| Zdroj: |
Journal of Thermal Analysis & Calorimetry; Feb2005, Vol. 79 Issue 2, p305-308, 4p |
| Abstrakt: |
The standard molar enthalpy of formation of crystalline bisdimethyldithiocarbamate zinc(II) complex, Zn[S2CN(CH3)2]2was determined through reaction-solution calorimetry in acetone, at 298 K. Using the standard molar enthalpy of formation of the gaseous chelate, the homolytic (-619.78±8.95 kJ mol-1) and heterolytic (-2747.71±8.95 kJ mol-1) mean enthalpies of zinc-sulphur bond dissociation were calculated. The investigation on the electronic structure involved the use of molecule orbital calculations. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Complementary Index |
| Externí odkaz: |
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