Highly Conjugated Bis(benzo[b]phosphole)‐P‐oxides: Synthesis and Electrochemical, Optical, and Computational Studies.

Autor:	D'Imperio, Nicolas, Pelliccioli, Valentina, Grecchi, Sara, Bossi, Alberto, Vasile, Francesca, Cauteruccio, Silvia, Arkhypchuk, Anna I., Kumar Gupta, Arvind, Orthaber, Andreas, Ott, Sascha, Licandro, Emanuela
Předmět:	CARBON-carbon bonds DOUBLE bonds PHOSPHINE oxides ISOMERS OPTICAL properties ATOMS
Zdroj:	European Journal of Organic Chemistry; 1/24/2023, Vol. 26 Issue 4, p1-9, 9p
Abstrakt:	The first examples of a π‐conjugated benzo[b]phosphole P‐oxide in which two phosphole P‐oxide units are connected by a carbon‐carbon double bond are described. The molecules are synthesized as E isomers with respect to the carbon‐carbon double bond and exist as stable cis and trans isomers (chiral and meso one respectively) relatively to the two stereogenic P atoms. The optical and electrochemical properties of both isomers have been investigated by experiment and computations. [ABSTRACT FROM AUTHOR]
Databáze:	Complementary Index
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